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Nucleophilic Reactions of Metal Carbonyl Anions with Fluorocarbons
Author(s) -
Bruce M. I.,
Stone F. G. A.
Publication year - 1968
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196807471
Subject(s) - nucleophile , chemistry , nucleophilic addition , metal , ion , photochemistry , metal ions in aqueous solution , metal carbonyl , carbon fibers , inorganic chemistry , polymer chemistry , organic chemistry , catalysis , materials science , composite number , composite material
This article describes the formation of carbon‐metal bonds by reacting carbonylmetalate ions with fluorocarbons. Complex formation depends on the nucleophilic behavior of the anions, and the susceptibility of fluorocarbons to this form of attack.