Premium
Carbonylation of Olefins under Mild Temperature Conditions in the Presence of Palladium Complexes
Author(s) -
Bittler K.,
Kutepow N. V.,
Neubauer D.,
Reis H.
Publication year - 1968
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196803291
Subject(s) - carbonylation , palladium , catalysis , chemistry , olefin fiber , phosphine , organic chemistry , amine gas treating , residue (chemistry) , nitrile , ligand (biochemistry) , medicinal chemistry , carbon monoxide , biochemistry , receptor
During a search for catalysts that allow carbonylation reactions on olefins to proceed below 100 °C, complex palladium( II ) compounds having the formula L m PdX n were found to be catalytically active. L denotes a ligand such as a phosphine, nitrile, amine, or olefin, X is an acid residue, and m+n is 3 or 4. The catalysts permit the carbonylation of heat‐sensitive compounds, as well as selective carbonylation of polyunsaturated olefins. The new process can also be carried out on the industrial scale, as is shown by the carbonylation of cyclododecatriene