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Syntheses of Thiocarbamates
Author(s) -
Walter W.,
Bode K.D.
Publication year - 1967
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196702811
Subject(s) - thiocarbamates , chemistry , organic chemistry , alkylation , hydrogen sulfide , sulfide , phenols , sulfur , catalysis
Abstract The methods suitable for the preparation of thiocarbamates are described and illustrated by examples and procedures. They are grouped under the following headings:1 Addition of Alcohols and Thiols to Isothiocyanates 2 Thioacylation of Amines(a) with chlorothioformates (b) with O,S ‐diesters of dithiocarbonic acid (c) with trithiocarbonates3 Thioacylation of Alcohols, Phenols, and Thiols(a) with thiocarbamoyl chlorides (b) with N,N ‐dialkylmercaptochloroformimidium chlorides (c) with N,N ′‐thiocarbonyldiimidazole4 Reaction of Thiocyanates and Cyanates with Hydrogen Sulfide 5 Alkylation of Metal Dithiocarbamates 6 Additions to Thiocyanic Acid