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Inorganic, Organometallic, and Organic Analogues of Carbenes
Author(s) -
Nefedov O. M.,
Manakov M. N.
Publication year - 1966
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196610211
Subject(s) - chemistry , group 2 organometallic chemistry , tin , boron , carbene , selenium , sulfur , main group element , germanium , silicon , divalent , inorganic chemistry , organometallic chemistry , nitrogen , heteroatom , organic chemistry , catalysis , molecule , transition metal , ring (chemistry)
This review deals with inorganic, organometallic, and organic compounds, as well as with elements, that on the basis of their electronic structure and their reactions can be regarded formally as analogues of carbenes. These “carbene analogues” include in particular the compounds of monovalent boron, aluminum, nitrogen, and phosphorus; those of divalent silicon, germanium, tin, and lead; atomic oxygen; atomic sulfur; and atomic selenium. The preparation and chemical properties of the carbenes and their analogues are compared.