Premium
Silicon‐Nitrogen Heterocycles
Author(s) -
Fink W.
Publication year - 1966
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196607601
Subject(s) - organosilicon , nitrogen , chemistry , silicon , ring (chemistry) , polymer chemistry , medicinal chemistry , organic chemistry
Great progress has recently been made in the chemistry of the silicon‐nitrogen bond C. Eaborn : Organosilicon Compounds. Butterworths, London 1960, p. 339.R. Fessenden and J. S. Fessenden , Chem. Reviews 61 , 361 (1961).K. A. Andrianov, I. Haiduc, and L. M. Khananashvili , Uspekhi Khim. 32 , 563 (1963); Chem. Abstr. 59 , 8782 (1963).U. Wannagat, Advances inorg. Chem. Radiochem. 6 , 265 (1964).I. Haiduc : Westep do Chemii Nieorganicznych Zwiazkow Pierscieniowyrh. WPN, Warsaw 1964, Chap. 10 (in Polish). . Whereas attention was formerly concentrated on open‐chain silazanes and silylamines, growing interest is now being shown in the cyclic SiN compounds. A major factor which has contributed to the rapid development in this field is the need for better polymers and liquids for use above 350 °C Cf. E. G. Rochow , Chim. et Ind. 85 , 897 (1961). . The present article deals with monomeric cyclic compounds containing at least one silicon‐nitrogen bond in the ring, as well as the polycyclic compounds derived from these.