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Applications and Limitations of Magnetic Methods in Free‐Radical Chemistry
Author(s) -
Müller E.,
Rieker A.,
Scheffler K.,
Moosmayer A.
Publication year - 1966
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196600061
Subject(s) - diradical , unpaired electron , radical , hyperfine structure , chemistry , free state , computational chemistry , photochemistry , organic chemistry , atomic physics , singlet state , physics , ancient history , history , excited state
The paper describes the application and limitations of magnetic methods to the problems of free‐radical chemistry (detection and quantitative investigation of the free‐radical state, relationships between structure and free‐radical formation, “distribution” of the unpaired electron, detection of mesomeric C, O, N, P, As, and Sn radicals, g‐factors, triplet states, and hyperfine structure). The problem of the diradical is described, and the paper closes with a discussion of the “Selwood effect”.