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The Chemistry of Nitrous Acid and of its Derivatives in Liquid Hydrogen Fluoride
Author(s) -
Seel F.
Publication year - 1965
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196506351
Subject(s) - hydrogen fluoride , chemistry , fluoride , fluorine , reagent , inorganic chemistry , hydrogen , hydrofluoric acid , organic chemistry , nitrous acid
The reaction of liquid hydrogen fluoride with nitrous acid, dinitrogen trioxide, dinitrogen tetroxide, and nitrosyl compounds leads to unexpectedly high‐boiling liquids which contain nitrosyl fluoride in the form of remarkably stable, electrolytically dissociated hydrogen fluoride solvates. Nitrosyl fluoride solvated by pure hydrogen fluoride is a new reagent, valuable in fluorine chemistry since it reacts with many elements and compounds to form fluorine derivatives of preparative importance.