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The Modes of Reaction of Ambident Catioins
Author(s) -
Hünig S.
Publication year - 1964
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196405481
Subject(s) - reagent , nucleophile , chemistry , competition (biology) , reaction conditions , computational chemistry , medicinal chemistry , photochemistry , organic chemistry , catalysis , ecology , biology
Abstract The effect of the nature of the coreactants and the reaction conditions on the ability of certain mesomeric cations to react with nucleophilic reagents to form isomeric products has been studied. The structures of the products isolated are determined by competition between a kinetically controlled but reversible reaction and a thermodynamically controlled reaction.