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A Synthetic Route to the Corrin System
Author(s) -
Bertele E.,
Boos H.,
Dunitz J. D.,
Elsinger F.,
Eschenmoser A.,
Felner I.,
Gribi H. P.,
Gschwend H.,
Meyer E. F.,
Pesaro M.,
Scheffold R.
Publication year - 1964
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196404901
Subject(s) - corrin , tetrafluoroborate , chemistry , nickel , organic chemistry , ring (chemistry) , catalysis , ionic liquid
The synthesis of the nickel(II) complex of (±)‐1,8,8,13,13‐pentamethyl‐trans‐corrin illustrates a synthetic route to the corrin system. Repeated use of triethyloxonium tetrafluoroborate in this synthesis demonstrates the preparative value of the trialkyloxonium salts discovered by Meerwein et al.