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Preparation of Carbon Tetrachloride from Phosgene
Author(s) -
Glemser O.,
Schröder J.,
KleineWeischede K.,
Meyer Boris,
Peuschel G.,
Flügel R.,
Velde D.
Publication year - 1963
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196306131
Subject(s) - phosgene , carbon tetrachloride , chlorine , chemistry , carbon monoxide , tetrachloride , activated charcoal , inorganic chemistry , charcoal , activated carbon , telomerization , catalysis , carbon fibers , organic chemistry , materials science , adsorption , composite number , tin , composite material
Carbon tetrachloride can be prepared from phosgene at 300–450°C. The catalysts for the reaction are transition metals of Groups V to VIII deposited on activated charcoal as carrier. Carbon monoxide and chlorine may be used as starting materials instead of phosgene.