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Syntheses with s ‐Triazine
Author(s) -
Grundmann Ch.
Publication year - 1963
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196303091
Subject(s) - triazine , nucleophile , reagent , chemistry , pyridine , pyrimidine , combinatorial chemistry , organic chemistry , stereochemistry , catalysis
The preparation and properties of s‐triazine are discussed. Nucleophilic reagents (even water) readily attack s‐triazine. Thus, open‐chain and heterocyclic compounds, e.g. formamidines, aminomethylene compounds, and triazole, pyridine, and pyrimidine deravatives are accessible from s‐triazine. With amidines and imido ethers substituted triazines are obtained (by trans‐triazination).The latter are formed via open‐chain intermediates.