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Cyclooligomerization of Butadiene and Transition Metal π‐Complexes
Author(s) -
Wilke G.,
Bogdanovič B.,
Borner P.,
Breil H.,
Hardt P.,
Heimbach P.,
Herrmann G.,
Kaminsky H.J.,
Keim W.,
Kröner M.,
Müller Herbert,
Müller Ernst Willi,
Oberkirch W.,
Schneider J.,
Stedefeder J.,
Tanaka K.,
Weyer K.,
Wilke G.
Publication year - 1963
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196301051
Subject(s) - transition metal , 1,3 butadiene , yield (engineering) , hydrocarbon , ethylene , catalysis , chemistry , metal , polymer chemistry , photochemistry , materials science , organic chemistry , metallurgy
Advances in the fields of synthesis and reactions of some medium‐sized hydrocarbon rings are reported and in connection therewith on novel π‐complexes of transition metals. Catalytic syntheses yield 1,5,9‐cyclododecatriene, 1,5‐cyclooctadiene, and 1,5‐cyclodecadiene either from butadiene or from butadiene and ethylene. The reactions proceed very readily.