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Azacalix[3]triazines: A Substructure of Triazine‐Based Graphitic Carbon Nitride Featuring Anion‐π Interactions
Author(s) -
Gong Hao,
Zhang Cheng,
Ogaki Takuya,
Inuzuka Hiroyuki,
Hashizume Daisuke,
Miyajima Daigo
Publication year - 2021
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202104467
Subject(s) - graphitic carbon nitride , substructure , triazine , ion , chemistry , carbon fibers , nitride , scope (computer science) , nanotechnology , chemical physics , computational chemistry , catalysis , materials science , organic chemistry , computer science , structural engineering , layer (electronics) , photocatalysis , composite number , engineering , composite material , programming language
Graphitic carbon nitride (GCN) has garnered broad research interest due to its unique catalytic properties. However, GCN, prepared by general methods, possesses myriad structural defects and it has been difficult to elucidate their intrinsic physical properties. We report the development of azacalix[3]triazines (AC3Ts), a substructure of triazine‐based GCN (Tz‐GCN). Despite the electron‐deficient natures of triazine, AC3Ts capture protons as organic superbases. We reveal the unique anion‐π interactions of AC3Ts that alters the ionization potentials of AC3Ts. To the best of our knowledge, these features have not yet been recognized for Tz‐GCN. These unveiled features of AC3Ts are expected to expand the usage scope and possibilities for GCNs.