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The Redox Journey of Iconic Ferrocene: Ferrocenium Dications and Ferrocenate Anions
Author(s) -
Walawalkar Mrinalini G.,
Pandey Priya,
Murugavel Ramaswamy
Publication year - 2021
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202101770
Subject(s) - ferrocene , redox , chemistry , metallocene , ring (chemistry) , solvent , combinatorial chemistry , inorganic chemistry , polymer chemistry , photochemistry , electrochemistry , organic chemistry , electrode , polymerization , polymer
The recent discoveries of both dicationic and monoanionic ferrocene derivatives throw light on the effect of the substituents on the C 5 ring as well as the choice of redox agents and solvent system in the preparation of previously believed to be difficult synthetic targets. These oxidized and reduced forms of ferrocene are of interest to spectroscopists, magnetochemists, and theoreticians.