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Bridging Thermal Catalysis and Electrocatalysis: Catalyzing CO 2 Conversion with Carbon‐Based Materials
Author(s) -
Koshy David M.,
Nathan Sindhu S.,
Asundi Arun S.,
Abdellah Ahmed M.,
Dull Samuel M.,
Cullen David A.,
Higgins Drew,
Bao Zhenan,
Bent Stacey F.,
Jaramillo Thomas F.
Publication year - 2021
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202101326
Subject(s) - electrocatalyst , catalysis , carbon fibers , chemistry , thermal , electrochemistry , kinetics , chemical engineering , materials science , nanotechnology , thermodynamics , electrode , organic chemistry , physics , composite material , quantum mechanics , composite number , engineering
Understanding the differences between reactions driven by elevated temperature or electric potential remains challenging, largely due to materials incompatibilities between thermal catalytic and electrocatalytic environments. We show that Ni, N‐doped carbon (NiPACN), an electrocatalyst for the reduction of CO 2 to CO (CO 2 R), can also selectively catalyze thermal CO 2 to CO via the reverse water gas shift (RWGS) representing a direct analogy between catalytic phenomena across the two reaction environments. Advanced characterization techniques reveal that NiPACN likely facilitates RWGS on dispersed Ni sites in agreement with CO 2 R active site studies. Finally, we construct a generalized reaction driving‐force that includes temperature and potential and suggest that NiPACN could facilitate faster kinetics in CO 2 R relative to RWGS due to lower intrinsic barriers. This report motivates further studies that quantitatively link catalytic phenomena across disparate reaction environments.