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sp 3 Bis ‐Organometallic Reagents via Catalytic 1,1‐Difunctionalization of Unactivated Olefins
Author(s) -
Sun ShangZheng,
Talavera Laura,
Spieß Philipp,
Day Craig S.,
Martin Ruben
Publication year - 2021
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202100810
Subject(s) - reagent , catalysis , chemistry , organometallic chemistry , group 2 organometallic chemistry , combinatorial chemistry , selectivity , scope (computer science) , medicinal chemistry , organic chemistry , molecule , computer science , programming language
A catalytic 1,1‐difunctionalization of unactivated olefins en route to sp 3 bis ‐organometallic B,B(Si)‐reagents is described. The protocol is characterized by exceptional reaction rates, mild conditions, wide scope, and exquisite selectivity pattern, constituting a new platform to access sp 3 bis ‐organometallics.