sp   3    Bis ‐Organometallic Reagents via Catalytic 1,1‐Difunctionalization of Unactivated Olefins | Zendy

Sun ShangZheng | Zendy; Talavera Laura | Zendy; Spieß Philipp | Zendy; Day Craig S. | Zendy; Martin Ruben | Zendy

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sp 3 Bis ‐Organometallic Reagents via Catalytic 1,1‐Difunctionalization of Unactivated Olefins

Author(s) -

Sun ShangZheng,

Talavera Laura,

Spieß Philipp,

Day Craig S.,

Martin Ruben

Publication year - 2021

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.202100810

Subject(s) - reagent , catalysis , chemistry , organometallic chemistry , group 2 organometallic chemistry , combinatorial chemistry , selectivity , scope (computer science) , medicinal chemistry , organic chemistry , molecule , computer science , programming language

A catalytic 1,1‐difunctionalization of unactivated olefins en route to sp 3 bis ‐organometallic B,B(Si)‐reagents is described. The protocol is characterized by exceptional reaction rates, mild conditions, wide scope, and exquisite selectivity pattern, constituting a new platform to access sp 3 bis ‐organometallics.

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