π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons | Zendy

MartínezAbadía Marta | Zendy; Strutyński Karol | Zendy; LermaBerlanga Belén | Zendy; Stoppiello Craig T. | Zendy; Khlobystov Andrei N. | Zendy; MartíGastaldo Carlos | Zendy; Saeki Akinori | Zendy; MelleFranco Manuel | Zendy; MateoAlonso Aurelio | Zendy

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π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons

Author(s) -

MartínezAbadía Marta,

Strutyński Karol,

LermaBerlanga Belén,

Stoppiello Craig T.,

Khlobystov Andrei N.,

MartíGastaldo Carlos,

Saeki Akinori,

MelleFranco Manuel,

MateoAlonso Aurelio

Publication year - 2021

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.202100434

Subject(s) - stacking , covalent bond , chemistry , aromaticity , covalent organic framework , topology (electrical circuits) , molecule , organic chemistry , mathematics , combinatorics

Three‐dimensional covalent organic frameworks (3D COFs) with a pcu topology have been obtained from distorted polycyclic aromatic hydrocarbons acting as triangular antiprismatic ( D 3 d ) nodes. Such 3D COFs are six‐fold interpenetrated as the result of interframework π‐stacking, which enable charge transport properties that are not expected for 3D COFs.

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