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π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons
Author(s) -
MartínezAbadía Marta,
Strutyński Karol,
LermaBerlanga Belén,
Stoppiello Craig T.,
Khlobystov Andrei N.,
MartíGastaldo Carlos,
Saeki Akinori,
MelleFranco Manuel,
MateoAlonso Aurelio
Publication year - 2021
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202100434
Subject(s) - stacking , covalent bond , chemistry , aromaticity , covalent organic framework , topology (electrical circuits) , molecule , organic chemistry , mathematics , combinatorics
Three‐dimensional covalent organic frameworks (3D COFs) with a pcu topology have been obtained from distorted polycyclic aromatic hydrocarbons acting as triangular antiprismatic ( D 3 d ) nodes. Such 3D COFs are six‐fold interpenetrated as the result of interframework π‐stacking, which enable charge transport properties that are not expected for 3D COFs.