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Hysteretic Control of Near‐infrared Transparency Using a Liquescent Radical Cation
Author(s) -
Suzuki Shuichi,
Yamaguchi Daiki,
Uchida Yoshiaki,
Naota Takeshi
Publication year - 2021
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202016930
Subject(s) - opacity , infrared , dissociation (chemistry) , photochemistry , chemistry , dimer , electron paramagnetic resonance , infrared spectroscopy , spectroscopy , materials science , analytical chemistry (journal) , nuclear magnetic resonance , optics , organic chemistry , physics , quantum mechanics
A liquescent dihydrophenazine radical cation, 1 .+ ⋅ NTf 2 − , showed drastic changes in near‐infrared (near‐IR) transparency and opaqueness through hysteretic phase transitions with no measurable degradation of the compound even under aerated conditions. During the heating and slow cooling process (0.5 K min −1 ), its electronic and magnetic properties were altered clearly and repeatedly changed between solid and liquid states. The liquid state was transparent to near‐IR light (940 nm), but the solid state was opaque, despite both samples exhibiting a similar green color under room light. Additionally, the liquid state was changed to a glass state under a fast cooling process (2–10 K min −1 ). UV/Vis/near‐IR and electron spin‐resonance spectroscopy revealed that these drastic changes were attributable to the dynamic dissociation and association of a π‐dimer structure for 1 .+ accompanying with the solid–liquid phase transitions even under the neat conditions.