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Photo‐responsive Helical Motion by Light‐Driven Molecular Motors in a Liquid‐Crystal Network
Author(s) -
Hou Jiaxin,
Mondal Anirban,
Long Guiying,
Haan Laurens,
Zhao Wei,
Zhou Guofu,
Liu Danqing,
Broer Dirk J.,
Chen Jiawen,
Feringa Ben L.
Publication year - 2021
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202016254
Subject(s) - molecular motor , molecular machine , liquid crystal , actuator , motion (physics) , bending , chirality (physics) , materials science , rotation around a fixed axis , nanotechnology , rotor (electric) , dopant , physics , chemical physics , computer science , mechanical engineering , classical mechanics , artificial intelligence , engineering , optoelectronics , chiral symmetry breaking , quantum mechanics , doping , quark , nambu–jona lasinio model , composite material
Controlling sophisticated motion by molecular motors is a major goal on the road to future actuators and soft robotics. Taking inspiration from biological motility and mechanical functions common to artificial machines, responsive small molecules have been used to achieve macroscopic effects, however, translating molecular movement along length scales to precisely defined linear, twisting and rotary motions remain particularly challenging. Here, we present the design, synthesis and functioning of liquid‐crystal network (LCN) materials with intrinsic rotary motors that allow the conversion of light energy into reversible helical motion. In this responsive system the photochemical‐driven molecular motor has a dual function operating both as chiral dopant and unidirectional rotor amplifying molecular motion into a controlled and reversible left‐ or right‐handed macroscopic twisting movement. By exploiting the dynamic chirality, directionality of motion and shape change of a single motor embedded in an LC‐network, complex mechanical motions including bending, walking and helical motion, in soft polymer materials are achieved which offers fascinating opportunities toward inherently photo‐responsive materials.