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Exploiting Ru‐Induced Lattice Strain in CoRu Nanoalloys for Robust Bifunctional Hydrogen Production
Author(s) -
Li Weidong,
Zhao Yunxuan,
Liu Yuan,
Sun Mingzi,
Waterhouse Geoffrey I. N.,
Huang Bolong,
Zhang Kan,
Zhang Tierui,
Lu Siyu
Publication year - 2021
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202013985
Subject(s) - bifunctional , catalysis , hydrolysis , hydrogen , ammonia borane , chemistry , hydrogen production , alloy , ruthenium , chemical engineering , organic chemistry , engineering
Designing bifunctional catalysts capable of driving the electrochemical hydrogen evolution reaction (HER) and also H 2 evolution via the hydrolysis of hydrogen storage materials such as ammonia borane (AB) is of considerable practical importance for future hydrogen economies. Herein, we systematically examined the effect of tensile lattice strain in CoRu nanoalloys supported on carbon quantum dots (CoRu/CQDs) on hydrogen generation by HER and AB hydrolysis. By varying the Ru content, the lattice parameters and Ru‐induced lattice strain in the CoRu nanoalloys could be tuned. The CoRu 0.5 /CQDs catalyst with an ultra‐low Ru content (1.33 wt.%) exhibited excellent catalytic activity for HER ( η =18 mV at 10 mA cm −2 in 1 M KOH) and extraordinary activity for the hydrolysis of AB with a turnover frequency of 3255.4 mol( H2 ) mol −1 (Ru) min −1 or 814.7 mol( H2 ) mol −1 (cat) min −1 at 298 K, respectively, representing one of the best activities yet reported for AB hydrolysis over a ruthenium alloy catalyst. Moreover, the CoRu 0.5 /CQDs catalyst displayed excellent stability during each reaction, including seven alternating cycles of HER and AB hydrolysis. Theoretical calculations revealed that the remarkable catalytic performance of CoRu 0.5 /CQDs resulted from the optimal alloy electronic structure realized by incorporating small amounts of Ru, which enabled fast interfacial electron transfer to intermediates, thus benefitting H 2 evolution kinetics. Results support the development of new and improved catalysts HER and AB hydrolysis.