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Cyclic Heterometallic Interactions formed from a Flexible Tripeptide Complex Showing Effective Antiferromagnetic Spin Coupling
Author(s) -
Miyake Ryosuke,
Suganuma Eri,
Kimura Shun,
Mori Hirotoshi,
Okabayashi Jun,
Kusamoto Tetsuro
Publication year - 2021
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202013373
Subject(s) - tripeptide , antiferromagnetism , crystallography , metal , chemistry , octahedron , materials science , crystal structure , condensed matter physics , organic chemistry , peptide , physics , biochemistry
Developing tunable motifs for heterometallic interactions should be beneficial for fabricating functional materials based on cooperative electronic communications between metal centers. Reported here is the efficient formation of cyclic heterometallic interactions from a complex containing an artificial tripeptide with metal binding sites on its main chain and side chains. X‐ray structural analysis and X‐ray absorption spectroscopy revealed that the cyclic metal–metal arrangements arise from the amide groups connecting four square‐planar Cu II centers and four octahedral Ni II centers in a cyclic manner. UV/Vis spectral studies suggested that this efficient formation was achieved by the selective formation of the square‐planar Cu II centers and a crystallization process. Magnetic measurements using SQUID clarified that the cyclic complex represented the S =2 spin state at low temperatures due to effective antiferromagnetic interactions between the Ni II and Cu II centers.