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Atomic‐Level Modulation of Electronic Density at Cobalt Single‐Atom Sites Derived from Metal–Organic Frameworks: Enhanced Oxygen Reduction Performance
Author(s) -
Chen Yuanjun,
Gao Rui,
Ji Shufang,
Li Haijing,
Tang Kun,
Jiang Peng,
Hu Haibo,
Zhang Zedong,
Hao Haigang,
Qu Qingyun,
Liang Xiao,
Chen Wenxing,
Dong Juncai,
Wang Dingsheng,
Li Yadong
Publication year - 2021
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202012798
Subject(s) - tafel equation , density functional theory , catalysis , cobalt , chemistry , electrochemistry , metal , moiety , atom (system on chip) , metal organic framework , computational chemistry , inorganic chemistry , stereochemistry , electrode , organic chemistry , embedded system , adsorption , computer science
Demonstrated here is the correlation between atomic configuration induced electronic density of single‐atom Co active sites and oxygen reduction reaction (ORR) performance by combining density‐functional theory (DFT) calculations and electrochemical analysis. Guided by DFT calculations, a MOF‐derived Co single‐atom catalyst with the optimal Co 1 ‐N 3 PS active moiety incorporated in a hollow carbon polyhedron (Co 1 ‐N 3 PS/HC) was designed and synthesized. Co 1 ‐N 3 PS/HC exhibits outstanding alkaline ORR activity with a half‐wave potential of 0.920 V and superior ORR kinetics with record‐level kinetic current density and an ultralow Tafel slope of 31 mV dec −1 , exceeding that of Pt/C and almost all non‐precious ORR electrocatalysts. In acidic media the ORR kinetics of Co 1 ‐N 3 PS/HC still surpasses that of Pt/C. This work offers atomic‐level insight into the relationship between electronic density of the active site and catalytic properties, promoting rational design of efficient catalysts.