Enantioselective Intermolecular Heck and Reductive Heck Reactions of Aryl Triflates, Mesylates, and Tosylates Catalyzed by Nickel | Zendy

Huang Xiaolei | Zendy; Teng Shenghan | Zendy; Chi Yonggui Robin | Zendy; Xu Wenqiang | Zendy; Pu Maoping | Zendy; Wu YunDong | Zendy; Zhou Jianrong Steve | Zendy

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Enantioselective Intermolecular Heck and Reductive Heck Reactions of Aryl Triflates, Mesylates, and Tosylates Catalyzed by Nickel

Author(s) -

Huang Xiaolei,

Teng Shenghan,

Chi Yonggui Robin,

Xu Wenqiang,

Pu Maoping,

Wu YunDong,

Zhou Jianrong Steve

Publication year - 2021

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.202011036

Subject(s) - heck reaction , aryl , chemistry , enantioselective synthesis , nickel , catalysis , cyclopentenone , organic chemistry , conjugate , enone , medicinal chemistry , palladium , mathematical analysis , alkyl , mathematics

Nickel‐catalyzed intermolecular Heck reaction of cycloalkenes proceeds well with aryl triflates, mesylates and tosylates in excellent enantiomeric ratios. The asymmetric reductive Heck reaction also works with a 2‐cyclopentenone ketal, which is equivalent to conjugate arylation of the enone itself.

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