Pentacyclic Nano‐Trefoil | Zendy

Ju Huiyeong | Zendy; Tsuruoka Yumiko | Zendy; Hayano Miho | Zendy; Lee Eunji | Zendy; Park KiMin | Zendy; Ikeda Mari | Zendy; Ishii Junichi | Zendy; Kuwahara Shunsuke | Zendy; Habata Yoichi | Zendy

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Pentacyclic Nano‐Trefoil

Author(s) -

Ju Huiyeong,

Tsuruoka Yumiko,

Hayano Miho,

Lee Eunji,

Park KiMin,

Ikeda Mari,

Ishii Junichi,

Kuwahara Shunsuke,

Habata Yoichi

Publication year - 2021

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.202010436

Subject(s) - benzene , trefoil , molecule , cyclen , chemistry , molar ratio , ligand (biochemistry) , solid state , stereochemistry , crystallography , organic chemistry , receptor , biochemistry , catalysis , archaeology , history

Tetra‐armed cyclen ( 1 ) bearing two 4‐(4′‐pyridyl)benzyl and two 3,5‐difluorobenzyl groups and its Ag + complexes were prepared and structurally characterized. The complexes formed between 1 and Ag + undergoes a reversible structural transformation between a 2:2 dimeric complex and a 3:5 pentacyclic trefoil complex with changes in the Ag + / 1 molar ratio. It was also revealed that the 3:5 trefoil complex could encapsulate benzene and [D 6 ]benzene selectively in solid‐state. The benzene‐included structures are stabilized by C−H⋅⋅⋅F−C interactions between the benzene molecule and the ligand molecule.

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