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Rational Assembly of Metallophilic Gold(I)–Lead(II) and Gold(I)–Gold(I) Puzzle Pieces
Author(s) -
LópezdeLuzuriaga José M.,
Monge Miguel,
Moreno Sonia,
Olmos M. Elena,
RodríguezCastillo María
Publication year - 2021
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202010095
Subject(s) - stacking , terpyridine , chemistry , crystallography , stereochemistry , nanotechnology , metal , materials science , organic chemistry
The assembly of two different building blocks, [{Au(C 6 F 5 ) 2 }{PbCl(terpy)}] (terpy=2,2′:6′:2′′‐terpyridine) and [{Au(C 6 F 5 ) 2 } 2 {Pb(terpy)}] n , acting as terminal or central pieces, respectively, gives rise to a decanuclear complex built via metallophilic and π‐stacking interactions in which the number of Au I ⋅⋅⋅Au I and Au I ⋅⋅⋅Pb II contacts is finely controlled.
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