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A Layered Cationic Aluminum Oxyhydroxide as a Highly Efficient and Selective Trap for Heavy Metal Oxyanions
Author(s) -
Bai Pu,
Dong Zhuoya,
Wang Shuang,
Wang Xiangyu,
Li Yue,
Wang Yunzheng,
Ma Yanhang,
Yan Wenfu,
Zou Xiaodong,
Yu Jihong
Publication year - 2020
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202005878
Subject(s) - oxyanion , cationic polymerization , layered double hydroxides , chemistry , aqueous solution , sorption , metal , inorganic chemistry , hydroxide , adsorption , catalysis , organic chemistry
Cationic framework materials, especially pure inorganic cationic frameworks that can efficiently and selectively capture harmful heavy metal oxyanions from aqueous solution are highly desired yet scarcely reported. Herein, we report the discovery of a 2D cationic aluminum oxyhydroxide, JU‐111, which sets a new benchmark for heavy metal oxyanion sorbents, especially for Cr VI . Its structure was solved based on 3D electron diffraction tomography data. JU‐111 shows fast sorption kinetics (ca. 20 min), high capture capacity (105.4 mg g −1 ), and broad working pH range (3–10) toward Cr VI oxyanions. Unlike layered double hydroxides (LDHs), which are poorly selective in the presence of CO 3 2− , JU‐111 retains excellent selectivity for Cr VI even under a large excess of CO 3 2− . These superior features coupled with the ultra‐low cost and environmentally benign nature make JU‐111 a promising candidate for toxic metal oxyanion remediation as well as other potential applications.