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[BO 2 ] − as a Synthon for the Generation of Boron‐Centered Carbamate and Carboxylate Isosteres
Author(s) -
Pécharman AnneFrédérique,
Hill Michael S.,
McMullin Claire L.,
Mahon Mary F.
Publication year - 2020
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202005674
Subject(s) - synthon , carboxylate , boron , chemistry , carbamate , medicinal chemistry , organic chemistry , radiochemistry
Oxoborane carbamate and carboxylate analogues result from the in situ trapping of [BO 2 ] − produced by elimination of 2,3‐dimethyl‐2‐butene from a pinacolatoboryl anion.