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Self‐Assembly of Perovskite CsPbBr 3 Quantum Dots Driven by a Photo‐Induced Alkynyl Homocoupling Reaction
Author(s) -
Li Hongbo,
Liu Xiangdong,
Ying Qifei,
Wang Chao,
Jia Wei,
Xing Xing,
Yin Lisha,
Lu Zhenda,
Zhang Kun,
Pan Yue,
Shi Zhan,
Huang Ling,
Jia Dianzeng
Publication year - 2020
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202004947
Subject(s) - perovskite (structure) , quantum dot , photoluminescence , self assembly , materials science , molecule , ligand (biochemistry) , carbon chain , nanotechnology , chemistry , photochemistry , chemical engineering , optoelectronics , crystallography , organic chemistry , receptor , biochemistry , engineering
Herein, we report the facile growth of three‐dimensional CsPbBr 3 perovskite supercrystals (PSCs) self‐assembled from individual CsPbBr 3 perovskite quantum dots (PQDs). By varying the carbon chain length of a surface‐bound ligand molecule, 1‐alkynyl acid, different morphologies of PSCs were obtained accompanied by an over 1000‐fold photoluminescence improvement compared with that of PQDs. Systematic analyses have shown, for the first time, that under UV irradiation, CsBr, the byproduct formed during PQDs synthesis, could effectively catalyze the homocoupling reaction between two alkynyl groups, which further worked as a driving force to push forward the self‐assembly of PQDs.