Premium
A Single‐Atom Manipulation Approach for Synthesis of Atomically Mixed Nanoalloys as Efficient Catalysts
Author(s) -
Zhou Xuan,
Li Kai,
Lin Yunxiang,
Song Li,
Liu Jincheng,
Liu Yu,
Zhang Lingling,
Wu Zhijian,
Song Shuyan,
Li Jun,
Zhang Hongjie
Publication year - 2020
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202004945
Subject(s) - catalysis , thermostability , nanoparticle , alloy , atom (system on chip) , noble metal , materials science , nanotechnology , solvent , chemical engineering , metal , transition metal , combinatorial chemistry , chemistry , metallurgy , organic chemistry , computer science , embedded system , engineering , enzyme
Synthesis of well‐defined atomically mixed alloy nanoparticles on desired substrates is an ultimate goal for their practical application. Herein we report a general approach for preparing atomically mixed AuPt, AuPd, PtPd, AuPtPd NAs(nanoalloys) through single‐atom level manipulation. By utilizing the ubiquitous tendency of aggregation of single atoms into nanoparticles at elevated temperatures, we have synthesized nanoalloys on a solid solvent with CeO 2 as a carrier and transition‐metal single atoms as an intermediate state. The supported nanoalloys/CeO 2 with ultra‐low noble metal content (containing 0.2 wt % Au and 0.2 wt % Pt) exhibit enhanced catalytic performance towards complete CO oxidation at room temperature and remarkable thermostability. This work provides a general strategy for facile and rapid synthesis of well‐defined atomically mixed nanoalloys that can be applied for a range of emerging techniques.