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Design of Bowl‐Shaped N ‐Hydroxyimide Derivatives as New Organoradical Catalysts for Site‐Selective C(sp 3 )−H Bond Functionalization Reactions
Author(s) -
Kato Terumasa,
Maruoka Keiji
Publication year - 2020
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202003982
Subject(s) - amination , catalysis , chemistry , selectivity , surface modification , hydrocarbon , combinatorial chemistry , organic chemistry , medicinal chemistry
A series of new bowl‐shaped N ‐hydroxyimide derivatives has been designed and used as selective organoradical catalysts. A number of these bowl‐shaped N ‐hydroxyimide derivatives exhibit excellent site‐selectivity in the amination of benzylic C(sp 3 )−H bonds in aromatic hydrocarbon substrates.