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Silver‐Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions
Author(s) -
Li ManBo,
Yang Ying,
Rafi Abdolrahim A.,
Oschmann Michael,
Grape Erik Svensson,
Inge A. Ken,
Córdova Armando,
Bäckvall JanE.
Publication year - 2020
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202001809
Subject(s) - catalysis , palladium , carbonylation , oxidative phosphorylation , chemistry , heterogeneous catalysis , chloride , oxidative addition , combinatorial chemistry , organic chemistry , carbon monoxide , biochemistry
A silver‐triggered heterogeneous Pd‐catalyzed oxidative carbonylation has been developed. This heterogeneous process exhibits high efficiency and good recyclability, and was utilized for the one‐pot construction of polycyclic compounds with multiple chiral centers. AgOTf was used to remove chloride ions in the heterogeneous catalyst Pd‐AmP‐CNC, thereby generating highly active Pd II , which results in high efficiency of the heterogeneous catalytic system.