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Metal‐like Ductility in Organic Plastic Crystals: Role of Molecular Shape and Dihydrogen Bonding Interactions in Aminoboranes
Author(s) -
Mondal Amit,
Bhattacharya Biswajit,
Das Susobhan,
Bhunia Surojit,
Chowdhury Rituparno,
Dey Somnath,
Reddy C. Malla
Publication year - 2020
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202001060
Subject(s) - materials science , crystallography , ductility (earth science) , molecule , slip (aerodynamics) , chemical physics , plastic crystal , transition metal , composite material , condensed matter physics , chemistry , phase transition , thermodynamics , physics , organic chemistry , creep , catalysis
Abstract Ductility is a common phenomenon in many metals but is difficult to achieve in molecular crystals. Organic crystals bend plastically on one or two face‐specific directions but fracture when stressed in any other arbitrary directions. An exceptional metal‐like ductility and malleability in the isomorphous crystals of two globular molecules, BH 3 NMe 3 and BF 3 NMe 3 , is reported, with characteristic tensile stretching, compression, twisting, and thinning. The mechanically deformed samples, which transition to lower symmetry phases, retain good long‐range order amenable to structure determination by single‐crystal X‐ray diffraction. Molecules in these high‐symmetry crystals interact through electrostatic forces (B − −N + ) to form columnar structures with multiple slip planes and weak dispersive forces between columns. On the other hand, the limited number of facile slip planes and strong dihydrogen bonding in BH 3 NHMe 2 negates ductility. Our study has implications for the design of soft ferroelectrics, solid electrolytes, barocalorics, and soft robotics.