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Emerging Cubic Chirality in γCD‐MOF for Fabricating Circularly Polarized Luminescent Crystalline Materials and the Size Effect
Author(s) -
Hu Liangyu,
Li Kun,
Shang Weili,
Zhu Xuefeng,
Liu Minghua
Publication year - 2020
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.202000589
Subject(s) - luminescence , chirality (physics) , void (composites) , materials science , circular polarization , crystallography , nanotechnology , chemical physics , chemistry , optoelectronics , optics , chiral symmetry , physics , composite material , quantum mechanics , nambu–jona lasinio model , quark , microstrip
The chiral feature of γCD‐MOF, and especially the emergent cubic void, was not unveiled so far. Now, through the host–guest interaction between γCD‐MOF and achiral luminophores with different charges and sizes, the unique cubic chirality of the emerging void in γCD‐MOF as well as a size effect on CPL induction are revealed for the first time. Numerous achiral luminophores could be integrated into γCD‐MOF and emitted significantly boosted circularly polarized luminescence. While the small sized luminophores preferred to be loaded into the intrinsic void of γCD, large ones were selectively encapsulated into the cubic void. Interestingly, when the size of the guest luminophores was close to the cube size, it showed strong negative CPL. Otherwise, either positive or negative CPL was induced.