Premium
Site‐Selective 1,2‐Dicarbofunctionalization of Vinyl Boronates through Dual Catalysis
Author(s) -
Sun ShangZheng,
Duan Yaya,
Mega Riccardo S.,
Somerville Rosie J.,
Martin Ruben
Publication year - 2020
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201916279
Subject(s) - regioselectivity , catalysis , chemistry , halide , boron , alkyl , combinatorial chemistry , dual role , dual (grammatical number) , modular design , organic chemistry , computer science , art , literature , operating system
A modular, site‐selective 1,2‐dicarbofunctionalization of vinyl boronates with organic halides through dual catalysis is described. This reaction proceeds under mild conditions and is characterized by excellent chemo‐ and regioselectivity. It thus represents a complementary new technique for preparing densely functionalized alkyl boron architectures from simple and accessible precursors.