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General Strategy for Synthesis of Ordered Pt 3 M Intermetallics with Ultrasmall Particle Size
Author(s) -
Zhang Bentian,
Fu Gengtao,
Li Yutao,
Liang Lecheng,
Grundish Nicholas S.,
Tang Yawen,
Goodenough John B.,
Cui Zhiming
Publication year - 2020
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201916260
Subject(s) - intermetallic , materials science , graphene , chemical engineering , nanoparticle , catalysis , particle size , oxide , annealing (glass) , porosity , nanotechnology , alloy , metallurgy , composite material , chemistry , organic chemistry , engineering
Controllable synthesis of atomically ordered intermetallic nanoparticles (NPs) is crucial to obtain superior electrocatalytic performance for fuel cell reactions, but still remains arduous. Herein, we demonstrate a novel and general hydrogel‐freeze drying strategy for the synthesis of reduced graphene oxide (rGO) supported Pt 3 M (M=Mn, Cr, Fe, Co, etc.) intermetallic NPs (Pt 3 M/rGO‐HF) with ultrasmall particle size (about 3 nm) and dramatic monodispersity. The formation of hydrogel prevents the aggregation of graphene oxide and significantly promotes their excellent dispersion, while a freeze‐drying can retain the hydrogel derived three‐dimensionally (3D) porous structure and immobilize the metal precursors with defined atomic ratio on GO support during solvent sublimation, which is not afforded by traditional oven drying. The subsequent annealing process produces rGO supported ultrasmall ordered Pt 3 M intermetallic NPs (≈3 nm) due to confinement effect of 3D porous structure. Such Pt 3 M intermetallic NPs exhibit the smallest particle size among the reported ordered Pt‐based intermetallic catalysts. A detailed study of the synthesis of ordered intermetallic Pt 3 Mn/rGO catalyst is provided as an example of a generally applicable method. This study provides an economical and scalable route for the controlled synthesis of Pt‐based intermetallic catalysts, which can pave a way for the commercialization of fuel cell technologies.