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A Stable Calcium Alumanyl
Author(s) -
Schwamm Ryan J.,
Coles Martyn P.,
Hill Michael S.,
Mahon Mary F.,
McMullin Claire L.,
Rajabi Nasir A.,
Wilson Andrew S. S.
Publication year - 2020
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201914986
Subject(s) - reactivity (psychology) , nucleophile , chemistry , rationalisation , potassium , calcium , stereochemistry , medicinal chemistry , organic chemistry , catalysis , medicine , alternative medicine , geometry , mathematics , pathology
A seven‐membered N , N ′‐heterocyclic potassium alumanyl nucleophile is introduced and utilised in the metathetical synthesis of Mg−Al and Ca−Al bonded derivatives. Both species have been characterised by experimental and theoretical means, allowing a rationalisation of the greater reactivity of the heavier group 2 species implied by an initial assay of their reactivity.