Premium
A Stable Calcium Alumanyl
Author(s) -
Schwamm Ryan J.,
Coles Martyn P.,
Hill Michael S.,
Mahon Mary F.,
McMullin Claire L.,
Rajabi Nasir A.,
Wilson Andrew S. S.
Publication year - 2020
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201914986
Subject(s) - calcium , chemistry , organic chemistry
A seven‐membered N , N ′‐heterocyclic potassium alumanyl nucleophile is introduced and utilised in the metathetical synthesis of Mg−Al and Ca−Al bonded derivatives. Both species have been characterised by experimental and theoretical means, allowing a rationalisation of the greater reactivity of the heavier group 2 species implied by an initial assay of their reactivity.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom