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A Dual Threat: Redox‐Activity and Electronic Structures of Well‐Defined Donor–Acceptor Fulleretic Covalent‐Organic Materials
Author(s) -
Leith Gabrielle A.,
Rice Allison M.,
Yarbrough Brandon J.,
Berseneva Anna A.,
Ly Richard T.,
Buck Charles N.,
Chusov Denis,
Brandt Amy J.,
Chen Donna A.,
Lamm Benjamin W.,
Stefik Morgan,
Stephenson Kenneth S.,
Smith Mark D.,
Vannucci Aaron K.,
Pellechia Perry J.,
Garashchuk Sophya,
Shustova Natalia B.
Publication year - 2020
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201914233
Subject(s) - redox , covalent bond , acceptor , stacking , materials science , electronic structure , nanotechnology , chemistry , chemical physics , computational chemistry , inorganic chemistry , organic chemistry , physics , condensed matter physics
The effect of donor (D)–acceptor (A) alignment on the materials electronic structure was probed for the first time using novel purely organic porous crystalline materials with covalently bound two‐ and three‐dimensional acceptors. The first studies towards estimation of charge transfer rates as a function of acceptor stacking are in line with the experimentally observed drastic, eight‐fold conductivity enhancement. The first evaluation of redox behavior of buckyball‐ or tetracyanoquinodimethane‐integrated crystalline was conducted. In parallel with tailoring the D‐A alignment responsible for “static” changes in materials properties, an external stimulus was applied for “dynamic” control of the electronic profiles. Overall, the presented D–A strategic design, with stimuli‐controlled electronic behavior, redox activity, and modularity could be used as a blueprint for the development of electroactive and conductive multidimensional and multifunctional crystalline porous materials.