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Vapor‐Phase Linker Exchange of the Metal–Organic Framework ZIF‐8: A Solvent‐Free Approach to Post‐synthetic Modification
Author(s) -
Marreiros João,
Van Dommelen Lenz,
Fleury Guillaume,
OliveiraSilva Rodrigo,
Stassin Timothée,
Iacomi Paul,
Furukawa Shuhei,
Sakellariou Dimitrios,
Llewellyn Philip L.,
Roeffaers Maarten,
Ameloot Rob
Publication year - 2019
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201912088
Subject(s) - linker , zeolitic imidazolate framework , metal organic framework , chemistry , solvent , phase (matter) , combinatorial chemistry , organic chemistry , adsorption , computer science , operating system
Abstract Zeolitic imidazolate frameworks (ZIFs) are a sub‐class of metal–organic frameworks (MOFs). Although generally stable, ZIFs can undergo post‐synthetic linker exchange (PSLE) in solution under mild conditions. Herein, we present a novel, solvent‐free approach to post‐synthetic linker exchange through exposure to linker vapor.