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The Fundamentals of Real‐Time Surface Plasmon Resonance/Electrogenerated Chemiluminescence
Author(s) -
Dinel MariePier,
Tartaggia Stefano,
Wallace Gregory Q.,
Boudreau Denis,
Masson JeanFrancois,
Polo Federico
Publication year - 2019
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201909806
Subject(s) - surface plasmon resonance , luminophore , electrochemiluminescence , excited state , plasmon , surface plasmon , photochemistry , localized surface plasmon , resonance (particle physics) , chemistry , cyclic voltammetry , luminescence , electron transfer , materials science , analytical chemistry (journal) , optoelectronics , electrode , electrochemistry , nanotechnology , nanoparticle , atomic physics , organic chemistry , physics
Abstract We report the integration of surface plasmon resonance (SPR), cyclic voltammetry and electrochemiluminescence (ECL) responses to survey the interfacial adsorption and energy transfer processes involved in ECL on a plasmonic substrate. It was observed that a Tween 80/tripropylamine nonionic layer formed on the gold electrode of the SPR sensor, while enhancing the ECL emission process, affects the electron transfer process to the luminophore, Ru(bpy) 3 2+ , which in turn has an impact on the plasmon resonance. Concomitantly, the surface plasmon modulated the ECL intensity, which decreased by about 40 %, due to an interaction between the excited state of Ru(bpy) 3 2+ and the plasmon. This occurred only when the plasmon was excited, demonstrating that the optically excited surface plasmon leads to lower plasmon‐mediated luminescence and that the plasmon interacts with the excited state of Ru(bpy) 3 2+ within a very thin layer.