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Synthesis of Arylacetaldehydes by Iridium‐Catalyzed Arylation of Vinylene Carbonate with Arylboronic Acids
Author(s) -
Wang Zhe,
Xue Fei,
Hayashi Tamio
Publication year - 2019
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201906148
Subject(s) - iridium , catalysis , aryl , chemistry , carbonate , carbon fibers , organic chemistry , polymer chemistry , combinatorial chemistry , materials science , alkyl , composite number , composite material
The one‐step synthesis of arylacetaldehydes by carbon–carbon bond formation between formylmethyl and aryl groups has been realized by the reaction of vinylene carbonate with arylboronic acids in the presence of an iridium/bisphosphine catalyst and a catalytic amount of tetrahydroxydiboron.