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[Am(C 5 Me 4 H) 3 ]: An Organometallic Americium Complex
Author(s) -
Goodwin Conrad A. P.,
Su Jing,
AlbrechtSchmitt Thomas E.,
Blake Anastasia V.,
Batista Enrique R.,
Daly Scott R.,
Dehnen Stefanie,
Evans William J.,
Gaunt Andrew J.,
Kozimor Stosh A.,
Lichtenberger Niels,
Scott Brian L.,
Yang Ping
Publication year - 2019
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201905225
Subject(s) - density functional theory , americium , spectroscopy , group 2 organometallic chemistry , chemistry , organometallic chemistry , yield (engineering) , nuclear magnetic resonance spectroscopy , crystallography , ab initio quantum chemistry methods , computational chemistry , ab initio , crystal structure , materials science , molecule , actinide , inorganic chemistry , stereochemistry , organic chemistry , physics , quantum mechanics , metallurgy
We report the small‐scale synthesis, isolated yield, single‐crystal X‐ray structure, 1 H NMR solution spectroscopy /solid‐state UV/Vis‐nIR spectroscopy, and density functional theory (DFT)/ab initio wave function theory calculations on an Am 3+ organometallic complex, [Am(C 5 Me 4 H) 3 ] ( 1 ). This constitutes the first quantitative data on Am−C bonding in a molecular species.