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Ag 10 Ti 28 ‐Oxo Cluster Containing Single‐Atom Silver Sites: Atomic Structure and Synergistic Electronic Properties
Author(s) -
Chen Shuai,
Chen ZheNing,
Fang WeiHui,
Zhuang Wei,
Zhang Lei,
Zhang Jian
Publication year - 2019
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201904680
Subject(s) - cluster (spacecraft) , catalysis , atom (system on chip) , metal , density functional theory , materials science , titanium , doping , binding energy , crystallography , nanotechnology , chemistry , computational chemistry , atomic physics , metallurgy , physics , organic chemistry , optoelectronics , computer science , programming language , embedded system
Supported single‐atom catalysts have been emerging as promising materials in a variety of energy catalysis applications. However, studying the role of metal–support interactions at the molecular level remains a major challenge, primarily due to the lack of precise atomic structures. In this work, by replacing the frequently used TiO 2 support with its molecular analogue, titanium‐oxo cluster (TOC), we successfully produced a new kind of Ti‐O material doped with single silver sites. The as‐obtained Ag 10 Ti 28 cluster, containing four exposed and six embedded Ag sites, is the largest noble‐metal‐doped Ti‐O cluster reported to date. Density functional theory (DFT) calculations show that the Ag 10 Ti 28 core exhibits properties distinct from those of metallic Ag‐based materials. This Ti‐O material doped with single Ag sites presents a high ϵ d and moderate CO binding capacity comparable to that of metallic Cu‐based catalysts, suggesting that it might display different catalytic performance from the common Ag‐based catalysts, for example, for CO 2 reduction. These results prove that the synergism of active surface metal atoms and the Ti‐O cluster support result in unique physical properties, which might open a new direction for single‐atom‐included catalysts.