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A General and Air‐tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis
Author(s) -
Magnin Guillaume,
Clifton Jamie,
Schoenebeck Franziska
Publication year - 2019
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201903765
Subject(s) - conjugated system , catalysis , palladium , monomer , polymerization , reagent , polymer , reactivity (psychology) , dimer , polymer chemistry , chemistry , materials science , combinatorial chemistry , nanotechnology , chemical engineering , photochemistry , organic chemistry , medicine , alternative medicine , pathology , engineering
While current M 0 /M II based polymerization strategies largely focus on fine‐tuning the catalyst, reagents and conditions for each and every monomer, this report discloses a single method that allows access to a variety of different conjugated polymers within seconds at room temperature. Key to this privileged reactivity is an air‐ and moisture stable dinuclear Pd I catalyst. The method is operationally simple, robust and tolerant to air.