Premium
A General and Air‐tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis
Author(s) -
Magnin Guillaume,
Clifton Jamie,
Schoenebeck Franziska
Publication year - 2019
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201903765
Subject(s) - conjugated system , catalysis , palladium , monomer , polymerization , reagent , polymer , reactivity (psychology) , dimer , polymer chemistry , chemistry , materials science , combinatorial chemistry , nanotechnology , chemical engineering , photochemistry , organic chemistry , medicine , alternative medicine , pathology , engineering
While current M 0 /M II based polymerization strategies largely focus on fine‐tuning the catalyst, reagents and conditions for each and every monomer, this report discloses a single method that allows access to a variety of different conjugated polymers within seconds at room temperature. Key to this privileged reactivity is an air‐ and moisture stable dinuclear Pd I catalyst. The method is operationally simple, robust and tolerant to air.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom