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Nitriding‐Interface‐Regulated Lithium Plating Enables Flame‐Retardant Electrolytes for High‐Voltage Lithium Metal Batteries
Author(s) -
Tan ShuangJie,
Yue Junpei,
Hu XinCheng,
Shen ZhenZhen,
Wang WenPeng,
Li JinYi,
Zuo TongTong,
Duan Hui,
Xiao Yao,
Yin YaXia,
Wen Rui,
Guo YuGuo
Publication year - 2019
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201903466
Subject(s) - electrolyte , anode , fire retardant , materials science , cathode , lithium metal , plating (geology) , electrode , metal , lithium (medication) , chemical engineering , nanotechnology , metallurgy , chemistry , medicine , endocrinology , geophysics , engineering , geology
Safety concerns are impeding the applications of lithium metal batteries. Flame‐retardant electrolytes, such as organic phosphates electrolytes (OPEs), could intrinsically eliminate fire hazards and improve battery safety. However, OPEs show poor compatibility with Li metal though the exact reason has yet to be identified. Here, the lithium plating process in OPEs and Li/OPEs interface chemistry were investigated through ex situ and in situ techniques, and the cause for this incompatibility was revealed to be the highly resistive and inhomogeneous interfaces. Further, a nitriding interface strategy was proposed to ameliorate this issue and a Li metal anode with an improved Li cycling stability (300 h) and dendrite‐free morphology is achieved. Meanwhile, the full batteries coupled with nickel‐rich cathodes, such as LiNi 0.8 Co 0.1 Mn 0.1 O 2 , show excellent cycling stability and outstanding safety (passed the nail penetration test). This successful nitriding‐interface strategy paves a new way to handle the incompatibility between electrode and electrolyte.