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Enhancing Activity and Reducing Cost for Electrochemical Reduction of CO 2 by Supporting Palladium on Metal Carbides
Author(s) -
Wang Jiajun,
Kattel Shyam,
Hawxhurst Christopher J.,
Lee Ji Hoon,
Tackett Brian M.,
Chang Kuan,
Rui Ning,
Liu ChangJun,
Chen Jingguang G.
Publication year - 2019
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201900781
Subject(s) - palladium , electrochemistry , density functional theory , palladium hydride , faraday efficiency , catalysis , carbide , transition metal , materials science , metal , hydride , chemical engineering , chemistry , inorganic chemistry , electrode , computational chemistry , metallurgy , organic chemistry , engineering
Electrochemical CO 2 reduction reaction (CO 2 RR) with renewable electricity is a potentially sustainable method to reduce CO 2 emissions. Palladium supported on cost‐effective transition‐metal carbides (TMCs) are studied to reduce the Pd usage and tune the activity and selectivity of the CO 2 RR to produce synthesis gas, using a combined approach of studying thin films and practical powder catalysts, in situ characterization, and density functional theory (DFT) calculations. Notably, Pd/TaC exhibits higher CO 2 RR activity, stability and CO Faradaic efficiency than those of commercial Pd/C while significantly reducing the Pd loading. In situ measurements confirm the transformation of Pd into hydride (PdH) under the CO 2 RR environment. DFT calculations reveal that the TMC substrates modify the binding energies of key intermediates on supported PdH. This work suggests the prospect of using TMCs as low‐cost and stable substrates to support and modify Pd for enhanced CO 2 RR activity.