Photoelectrochemical C−H Alkylation of Heteroarenes with Organotrifluoroborates | Zendy

Yan Hong | Zendy; Hou ZhongWei | Zendy; Xu HaiChao | Zendy

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Photoelectrochemical C−H Alkylation of Heteroarenes with Organotrifluoroborates

Author(s) -

Yan Hong,

Hou ZhongWei,

Xu HaiChao

Publication year - 2019

Publication title -

angewandte chemie

Language(s) - English

Resource type - Journals

eISSN - 1521-3757

pISSN - 0044-8249

DOI - 10.1002/ange.201814488

Subject(s) - alkylation , chemistry , photoredox catalysis , chemoselectivity , electrocatalyst , catalysis , primary (astronomy) , surface modification , alkyl , radical , combinatorial chemistry , organic chemistry , electrochemistry , photocatalysis , electrode , physics , astronomy

A photoelectrochemical method for the C−H alkylation of heteroarenes with organotrifluoroborates has been developed. The merger of electrocatalysis and photoredox catalysis provides a chemical oxidant‐free approach for the generation and functionalization of alkyl radicals from organotrifluoroborates. A variety of heteroarenes were functionalized using primary, secondary, and tertiary alkyltrifluoroborates with excellent regio‐ and chemoselectivity.

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