The Complex Coordination Landscape of a Digold(I) U‐Shaped Metalloligand

A U‐shaped di‐gold metallotweezer with two pyrene‐imidazolylidene edges and a xanthenyl‐bis‐alkynyl connector was prepared. This metallotweezer acts as metalloligand in the presence of Cu + , Tl + , or Ag + , showing three clearly distinct coordination patterns depending on the cation used. The coordination to Cu + leads to a complex in which the metalloligand is coordinated in a pincer form. The reaction with Tl + affords a complex in which the ligand is acting as a ϰ 2 ‐( trans )‐chelate ligand. The reaction with Ag + leads to a self‐assembled structure, with two silver cations encased inside the cavity of a duplex structure formed by two self‐assembled metallotweezers.