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In‐Plane Epitaxial Growth of Highly c ‐Oriented NH 2 ‐MIL‐125(Ti) Membranes with Superior H 2 /CO 2 Selectivity
Author(s) -
Sun Yanwei,
Liu Yi,
Caro Jürgen,
Guo Xinwen,
Song Chunshan,
Liu Yi
Publication year - 2018
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201810088
Subject(s) - membrane , selectivity , epitaxy , materials science , seeding , chemical engineering , monolayer , crystallography , chemistry , nanotechnology , catalysis , organic chemistry , layer (electronics) , thermodynamics , physics , biochemistry , engineering
Preferred‐orientation control has significant impact on the separation performance of MOF membranes. Under most conditions the preferred orientation of MOF membranes is dominated by the Van der Drift mechanism of evolutionary growth selection so that the obtained orientation may not be optimized for practical application. In this study, highly c ‐oriented NH 2 ‐MIL‐125 membranes were prepared on porous α‐alumina substrates by combining oriented seeding and controlled in‐plane epitaxial growth. Dynamic air–liquid interface‐assisted self‐assembly of c ‐oriented NH 2 ‐MIL‐125(Ti) seed monolayers, the use of layered TiS 2 as the metal precursor, and single‐mode microwave heating were crucial in ensuring the preferred c ‐orientation while simultaneously suppressing undesired twin growth. Owing to reduced grain boundary defects, the prepared c ‐oriented membranes showed an ideal H 2 /CO 2 selectivity of 24.8, which was 6.1 times higher than that of their randomly oriented counterparts under similar operating conditions.