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Observation of Carbodicarbene Ligand Redox Noninnocence in Highly Oxidized Iron Complexes
Author(s) -
Chan SiuChung,
Gupta Puneet,
Engelmann Xenia,
Ang Zhi Zhong,
Ganguly Rakesh,
Bill Eckhard,
Ray Kallol,
Ye Shengfa,
England Jason
Publication year - 2018
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201809158
Subject(s) - redox , chemistry , ligand (biochemistry) , antiferromagnetism , crystallography , singlet state , spectroscopy , non innocent ligand , photochemistry , inorganic chemistry , atomic physics , biochemistry , physics , receptor , quantum mechanics , excited state , condensed matter physics
To probe the possibility that carbodicarbenes (CDCs) are redox active ligands, all four members of the redox series [Fe( 1 ) 2 ] n + ( n =2–5) were synthesized, where 1 is a neutral tridentate CDC. Through a combination of spectroscopy and DFT calculations, the electronic structure of the pentacation is shown to be [Fe III ( 1 .+ ) 2 ] 5+ ( S = 1 / 2 ). That of [Fe( 1 ) 2 ] 4+ is more ambiguous, but it has significant contributions from the open‐shell singlet [Fe III ( 1 )( 1 .+ )] 4+ ( S =0). The observed spin states derive from antiferromagnetic coupling of their constituent low‐spin iron(III) centres and cation radical ligands. This marks the first time redox activity has been observed for carbones and expands the diverse chemical behaviour known for these ligands.