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A Long‐Cycle‐Life Self‐Doped Polyaniline Cathode for Rechargeable Aqueous Zinc Batteries
Author(s) -
Shi HuaYu,
Ye YinJian,
Liu Kuan,
Song Yu,
Sun Xiaoqi
Publication year - 2018
Publication title -
angewandte chemie
Language(s) - English
Resource type - Journals
eISSN - 1521-3757
pISSN - 0044-8249
DOI - 10.1002/ange.201808886
Subject(s) - polyaniline , faraday efficiency , cathode , electrolyte , electrochemistry , materials science , aqueous solution , zinc , chemical engineering , dopant , inorganic chemistry , polymer , conductive polymer , electrode , doping , chemistry , polymerization , organic chemistry , composite material , metallurgy , optoelectronics , engineering
Rechargeable aqueous zinc batteries are promising energy‐storage systems for grid applications. Highly conductive polyaniline (PANI) is a potential cathode, but it tends to deactivate in electrolytes with low acidity (i.e. pH >1) owing to deprotonation of the polymer. In this study, we synthesized a sulfo‐self‐doped PANI electrode by a facile electrochemical copolymerization process. The −SO 3 − self‐dopant functions as an internal proton reservoir to ensure a highly acidic local environment and facilitate the redox process in the weakly acidic ZnSO 4 electrolyte. In a full zinc cell, the self‐doped PANI cathode provided a high capacity of 180 mAh g −1 , excellent rate performance of 70 % capacity retention with a 50‐fold current‐density increase, and a long cycle life of over 2000 cycles with coulombic efficiency close to 100 %. Our study opens a door for the use of conducting polymers as cathode materials for high‐performance rechargeable zinc batteries.